Current studies show that reservoirs are responsible for emissions of greenhouse gases (St. Louis et al. 2000, Duchemin et al. 2002, Soumis et al. 2004, Abril et al. 2005, Lima et al. 2008). Surface waters of aquatic ecosystems exhibit supersaturated dissolved CO2 (Cole 1999, Richey et al. 2002) because respiration based on both autochthonous and allocthonous organic carbon usually exceeds primary production (del Giorgio et al. 1997, Cole 1999, Jonsson et al. 2003). Dissolved organic carbon transported to the aquatic ecosystem from the drainage basin usually remains biologically refractory. Upon exposure to sunlight in a relatively well-lit aquatic environment, however, terrigenous organic carbon might undergo photolytic degradation and become more labile (Cole 1999). In spite of photomineralization, carbon dioxide effluxes may also result from methanotrophic activities (Frenzel et al. 1990, Abe et al. 2005, Lima 2005) associated with diel oxygen production via photosynthesis (King 1990, Lima et al. 2005a). Moreover, diel changes in sunlight may also affect dissolved gas solubility and, in particular, surface water density, leading to convection during cooling events (MacIntyre et al. 2001). We evaluated possible roles of sunlight on the daily variability of CH4 and CO2 diffusive fluxes from Corumba reser- ´ voir in Brazil. Our results support that CO2 and CH4 emissions in Corumba are substantially influenced by sunlight- ´ induced processes, although we cannot precisely identify the primary variables inducing diel changes
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